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Beilstein J. Org. Chem. 2013, 9, 106–117, doi:10.3762/bjoc.9.14
Graphical Abstract
Figure 1: Chemical structure of fenitrothion (1).
Figure 2: Representative TGA (top) and DSC (bottom) traces for DIMEB·1.
Figure 3: The asymmetric unit in DIMEB•1 viewed along [010] (top) and [100] (bottom). H atoms are omitted for...
Figure 4: The host molecules in the asymmetric unit of DIMEB·1 with the labelling of both residues and atoms ...
Figure 5: The rotamers of 1 occupying the cavity of host molecule A. Common atoms have labels with suffix A, ...
Figure 6: Stereoview of the three disordered guest components that occupy the cavity of host molecule B. Gues...
Figure 7: Space-filling diagrams showing the relative orientations of guest molecules within the cavities of ...
Figure 8: Packing diagrams of the DIMEB·1 structure, viewed along [100] (left) and [010] (right). The symmetr...
Figure 9: Induced circular dichroism (a) and UV–vis (b) spectra of 1 in the presence of β-CD (10 mM, green), ...
Scheme 1: Reaction of fenitrothion in basic media.
Figure 10: Plot of kobs versus [DIMEB] for the hydrolysis reaction of fenitrothion with HO– at different conce...
Scheme 2: Mechanism of the hydrolysis reaction of 1 mediated by DIMEB.